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Correct answer: D
Explanation
Butane is correct because LPG is primarily a mixture of propane and butane. Methane is incorrect because it is the main component of natural gas, not typically the major constituent of LPG. Ethane is incorrect because while it can be present, it is not the primary major constituent listed for standard LPG. Hydrogen is incorrect because it is generally not considered a major constituent of commercial LPG.