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Correct answer: D
Explanation
Raoult's law states $\Delta P = X_{solute} imes P^0$. If $\Delta P$ doubles to 20 mm Hg, and $P^0$ is constant, the mole fraction of solute must double from 0.2 to 0.4. The mole fraction of solvent is $1 - X_{solute}$, so it becomes $1 - 0.4 = 0.6$.